Product Identification
【Product Name】4-Fluorobenzonitrile  对氟苯腈
【Synonyms】p-Fluorobenzonitrile
【CAS】1194-02-1
【Formula】C7H4FN
【Molecular Weight】121.11
【EINECS】214-784-9
【RTECS】DI4368500
【RTECS Class】Drug
【Beilstein/Gmelin】2041517
【Beilstein Reference】4-09-00-00954

Physical and Chemical Properties
【Appearance】White solid.
【Solubility in water】Slightly soluble
【Melting Point】37 - 40
【Boiling Point】188
【Vapor Pressure】0.56 (25 C)
【Density】1.107 g/cm3(55.4 C)
【Partition Coefficient】1.7
【Heat Of Vaporization】42.6 kJ/mol
【Refractive Index】1.4925 (55 C)

First Aid Measures
【Ingestion】If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage
【Storage】Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification
【Ingestion】May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
【Inhalation】The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation.
【Skin】May cause skin irritation.
【Eyes】Dust may cause mechanical irritation.
【EC Risk Phrase】R 20/21/22
【EC Safety Phrase】S 28 36/37
【UN (DOT)】2811

Exposure Controls/Personal Protection
【Personal Protection】Eyes: Wear appropriate protective eyeglasses or chemical safety ggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures
【Flash Point】65
【Fire Fighting】Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures
【Small spills/leaks】Wash area with soap and water. Sweep up, then place into a suitable container for disposal.

Stability and Reactivity
【Stability】Stable under normal temperatures and pressures.
【Incompatibilities】Strong oxidizing agents, strong acids, strong bases.
【Decomposition】Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, cyanide fumes, hydrogen fluoride, fluoride fumes.

Transport Information
【UN Number】2811
【HS Code】2926 90 95